Entropy and Energy
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Statistical Entropy |
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Statistical Entropy: The application of probability theory to the thermodynamic principle of entropy. |
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The number of equivalent microstates (possible ways a given condition to occur) is denoted as W. |
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Entropy is denoted as S |
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k is the Boltzmann Constant = 1.38 X 10-23 JL-1 |
S = k ln W |
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This shows that entropy is a measure of the disorder of a system. |
| When energy is applied to a system how it affects entropy shown by the following formula. The formula shows what is need to produce order from disorder. |
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Number of equivalent microstates of the applied energy is We |
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Number of initial equivalent microstates of the system is Ws |
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The change in entropy is denoted as DS |
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This shows the general direction that applying energy to a system will move the entropy of that system and maximum change in entropy |
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This principle can be expressed in the following statements. |
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If energy is applied to a system in a manner more ordered than that system’s degree of order then it increases the system’s order decreasing the entropy of that system. |
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If energy is applied to a system in a manner more disordered than that system’s degree of disorder then it increases the system’s disorder increasing the entropy of that system. |
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This program provides illustrates the principle of reducing entropy
and there by producing order from disorder Convention 1: W is used instead of W since Greek letters could not be used. Convention 2: The value of W and S are not adjusted for the number of particles to avoid extremely large numbers. This convention do not change the how well it illustrates
the participle of
order from disorder.. |
Click on the image below to run program.Works only in windows. |
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